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dc.creatorBožić, Bojan
dc.creatorLović, Jelena
dc.creatorBanjac, Nebojsa
dc.creatorVitnik, Željko
dc.creatorVitnik, Vesna
dc.creatorMijin, Dušan
dc.creatorUšćumlić, Gordana
dc.creatorAvramov Ivić, Milka
dc.date.accessioned2019-01-30T17:57:34Z
dc.date.available2019-01-30T17:57:34Z
dc.date.issued2018
dc.identifier.issn1452-3981
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2300
dc.description.abstractA series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.en
dc.publisherEsg, Belgrade
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsopenAccess
dc.sourceInternational Journal of Electrochemical Science
dc.subjectDiphenylsuccinimideen
dc.subjectThreephenylsuccinimideen
dc.subjectVoltammetryen
dc.subjectQuantum chemical calculationsen
dc.subjectReaction mechanismsen
dc.titleVoltammetric and Quantum Investigation of Selected Succinimidesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЛовић, Јелена; Мијин, Дукин; Витник, Весна; Витник, Жељко; Бањац, Небојса; Усцумлиц, Гордана; Aврамов Ивић, Милка; Бозиц, Бојан;
dc.citation.volume13
dc.citation.issue5
dc.citation.spage4285
dc.citation.epage4297
dc.citation.other13(5): 4285-4297
dc.citation.rankM23
dc.identifier.doi10.20964/2018.05.54
dc.identifier.rcubConv_3953
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8693/2298.pdf
dc.identifier.scopus2-s2.0-85046802281
dc.identifier.wos000436257800020
dc.type.versionpublishedVersion


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