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dc.creatorCvetković, Vesna S.
dc.creatorJovicevic, Niko
dc.creatorStevanović, Jasmina
dc.creatorPavlović, Miomir
dc.creatorVukićević, Nataša
dc.creatorStevanovic, Zoran
dc.creatorJovićević, Jovan N.
dc.date.accessioned2019-01-30T17:55:06Z
dc.date.available2019-01-30T17:55:06Z
dc.date.issued2017
dc.identifier.issn2075-4701
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2181
dc.description.abstractMagnesium underpotential deposition on gold electrodes from magnesium nitrate-ammonium nitrate melts has been investigated. Linear sweep voltammetry and potential step were used as electrochemical techniques. Scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD) were used for characterization of obtained electrode surfaces. It was observed that reduction processes of nitrate, nitrite and traces of water (when present), in the Mg underpotential range studied, proceeded simultaneously with magnesium underpotential deposition. There was no clear evidence of Mg/Au alloy formation induced by Mg UPD from the melt made from eutectic mixture [Mg(NO3)(2).6H(2)O + NH4NO3.XH2O]. However, EDS and XRD analysis showed magnesium present in the gold substrate and four different Mg/Au alloys being formed as a result of magnesium underpotential deposition and interdiffusion between Mg deposit and Au substrate from the melt made of a nonaqueous [Mg(NO3)(2) + NH4NO3] eutectic mixture at 460 K.en
dc.publisherMDPI AG
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//
dc.rightsopenAccess
dc.sourceMetals
dc.subjectmagnesium/gold alloysen
dc.subjectunderpotential depositionen
dc.subjectmagnesium nitrate meltsen
dc.titleMagnesium-Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Meltsen
dc.typearticle
dc.rights.licenseBY
dcterms.abstractПавловић, Миомир; Стевановиц, Зоран; Јовицевиц, Јован Н.; Стевановић, Јасмина; Вукићевић, Наташа; Јовицевиц, Нико; Цветковић, Весна С.;
dc.citation.volume7
dc.citation.issue3
dc.citation.other7(3):
dc.citation.rankM22
dc.identifier.doi10.3390/met7030095
dc.identifier.rcubConv_3694
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8593/2179.pdf
dc.identifier.scopus2-s2.0-85015813104
dc.identifier.wos000397261600027
dc.type.versionpublishedVersion


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