Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study
Filipovic, Nenad R.
Rodić, Marko V.
Article (Published version)
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Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.
Keywords:X-ray crystal structure / cobalt(III) / Schiff base / antioxidant activity / DFT / Fukui
Source:Journal of the Serbian Chemical Society, 2017, 82, 7-8, 825-839
- Serbian Chemical Soc, Belgrade