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dc.creatorRomanović, Mima
dc.creatorČobeljić, Božidar
dc.creatorPevec, Andrej
dc.creatorTurel, Iztok
dc.creatorGrubišić, Sonja
dc.creatorRadanović, Dušanka
dc.creatorAnđelković, Katarina
dc.creatorMilenković, Marina
dc.creatorMilenković, Milica R.
dc.date.accessioned2019-01-30T17:53:39Z
dc.date.available2019-01-30T17:53:39Z
dc.date.issued2017
dc.identifier.issn0095-8972
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/2109
dc.description.abstractThe chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .en
dc.publisherTaylor & Francis Ltd, Abingdon
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS//
dc.relationCOST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
dc.relationCOST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
dc.relationSlovenian Research Agency [P1-0175]
dc.rightsrestrictedAccess
dc.sourceJournal of Coordination Chemistry
dc.subjectCd(II) complexesen
dc.subjecthydrazonesen
dc.subjectcrystal structureen
dc.subjectantimicrobial activityen
dc.subjectDFTen
dc.titleSynthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagenten
dc.typearticle
dc.rights.licenseARR
dcterms.abstractПевец, Aндреј; Миленковиц, Марина; Грубишић, Соња; Романовиц, Мима Ц.; Миленковиц, Милица Р.; Турел, Изток; Цобељиц, Бозидар; Aнђелковиц, Катарина; Радановић, Душанка;
dc.citation.volume70
dc.citation.issue21
dc.citation.spage3702
dc.citation.epage3714
dc.citation.other70(21): 3702-3714
dc.citation.rankM23
dc.description.otherThe peer-reviewed version: [http://cer.ihtm.bg.ac.rs/handle/123456789/3122]
dc.identifier.doi10.1080/00958972.2017.1405262
dc.identifier.scopus2-s2.0-85034657439
dc.identifier.wos000418940000010
dc.type.versionpublishedVersion


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