Приказ основних података о документу
Electrochemical behavior of palladium modified amino-functionalized macroporous copolymer
dc.creator | Marković, Bojana | |
dc.creator | Maksin, Danijela | |
dc.creator | Mojović, Zorica | |
dc.creator | Vuković, Zorica | |
dc.creator | Nastasović, Aleksandra | |
dc.creator | Jovanović, Dušan M. | |
dc.date.accessioned | 2019-01-30T17:53:01Z | |
dc.date.available | 2019-01-30T17:53:01Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1572-6657 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/2079 | |
dc.description.abstract | In this study, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) was synthesized by suspension copolymerization, functionalized by ring-opening reaction of the pendant epoxy groups with diethylene triamine and used for immobilization of Pd(II) ions from chloride and nitrate solutions under batch experimental condition. The amino-functionalized sample and samples with immobilized Pd(II) ions were characterized by Fourier transform infrared spectroscopy (FTIR) analysis and scanning energy-dispersive X-ray spectroscopy (SEM-EDX). The electrochemical behavior of electrodes composed of synthesized samples was tested in 0.1 M H2SO4 by means of cyclic voltammetry (CV). The shape of recorded CV showed dependence on the type of Pd-salt used for Pd immobilization. The reaction of oxidation of 4-chlorophenol (4-CP) from 0.1 M H2SO4 at investigated samples was also studied. Electrooxidation of 4-CP resulted in passivation and formation of reversible hydroquinone/benzoquinone on both investigated electrodes, although hydroquinone/benzoquinone formation was more pronounced on Pd immobilized from nitrite solution. | en |
dc.publisher | Elsevier | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43001/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Electroanalytical Chemistry | |
dc.subject | PGME | en |
dc.subject | Palladium | en |
dc.subject | Chlorophenol | en |
dc.subject | Electrooxidation | en |
dc.title | Electrochemical behavior of palladium modified amino-functionalized macroporous copolymer | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Настасовић, Aлександра; Марковић, Бојана; Вуковић, Зорица; Јовановиц, Дусан М.; Максин, Данијела Д.; Мојовић, Зорица; | |
dc.citation.volume | 786 | |
dc.citation.spage | 94 | |
dc.citation.epage | 101 | |
dc.citation.other | 786: 94-101 | |
dc.citation.rank | M21 | |
dc.description.other | The peer-reviewed version: [http://cer.ihtm.bg.ac.rs/handle/123456789/3019] | |
dc.identifier.doi | 10.1016/j.jelechem.2017.01.018 | |
dc.identifier.scopus | 2-s2.0-85009183692 | |
dc.identifier.wos | 000394063600014 | |
dc.type.version | publishedVersion |