Synthesis of vinyldihydropyran by cooperative catalysis
Apstrakt
Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.
Ključne reči:
dihydropyran / cooperative catalysis / cyclization / organopalladium reagentsIzvor:
Journal of the Serbian Chemical Society, 2016, 81, 12, 1335-1343Izdavač:
- Serbian Chemical Soc, Belgrade
Finansiranje / projekti:
DOI: 10.2298/JSC161102103V
ISSN: 0352-5139
WoS: 000392946100001
Scopus: 2-s2.0-85009739628
Institucija/grupa
IHTMTY - JOUR AU - Vulović, Bojan AU - Maric, Ivana AU - Matović, Radomir AU - Saičić, Radomir N. PY - 2016 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2050 AB - Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Synthesis of vinyldihydropyran by cooperative catalysis VL - 81 IS - 12 SP - 1335 EP - 1343 DO - 10.2298/JSC161102103V ER -
@article{ author = "Vulović, Bojan and Maric, Ivana and Matović, Radomir and Saičić, Radomir N.", year = "2016", abstract = "Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Synthesis of vinyldihydropyran by cooperative catalysis", volume = "81", number = "12", pages = "1335-1343", doi = "10.2298/JSC161102103V" }
Vulović, B., Maric, I., Matović, R.,& Saičić, R. N.. (2016). Synthesis of vinyldihydropyran by cooperative catalysis. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 81(12), 1335-1343. https://doi.org/10.2298/JSC161102103V
Vulović B, Maric I, Matović R, Saičić RN. Synthesis of vinyldihydropyran by cooperative catalysis. in Journal of the Serbian Chemical Society. 2016;81(12):1335-1343. doi:10.2298/JSC161102103V .
Vulović, Bojan, Maric, Ivana, Matović, Radomir, Saičić, Radomir N., "Synthesis of vinyldihydropyran by cooperative catalysis" in Journal of the Serbian Chemical Society, 81, no. 12 (2016):1335-1343, https://doi.org/10.2298/JSC161102103V . .