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dc.creatorNikolić, Nebojša
dc.creatorStevanović, Sanja
dc.creatorBrankovic, Goran
dc.date.accessioned2019-01-30T17:52:23Z
dc.date.available2019-01-30T17:52:23Z
dc.date.issued2016
dc.identifier.issn1003-6326
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2047
dc.description.abstractThe processes of nucleation and growth of lead from the dilute electrolytes on copper substrates were investigated by chronoamperometry and by scanning electron microscopic (SEM) analysis of the deposits obtained in the potentiostatic regime of electrolysis. In the dependence of electrodeposition conditions, the nucleation of Pb followed either progressive or instantaneous type. The type of nucleation changed from progressive to instantaneous one with increasing the concentration of Pb(II) ions and the overpotential of electrodeposition. Regardless of the type nucleation, a novel type of Pb particles like cobweb was formed by the potentiostatic electrodeposition in the moment of nucleation and at the early stages of growth. On the basis of the shape of cobweb-like particles and the electrodeposition conditions leading to their formation, these particles were situated in the group of spongy-like ones. Also, comparative morphological analysis of Pb deposits obtained in the conditions of progressive and instantaneous nucleation confirmed the existence of two limiting types of nucleation.en
dc.publisherElsevier Science Bv, Amsterdam
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//
dc.rightsrestrictedAccess
dc.sourceTransactions of Nonferrous Metals Society of China
dc.subjectelectrodepositionen
dc.subjectleaden
dc.subjectnucleationen
dc.subjectgrowthen
dc.subjectmorphologyen
dc.subjectchronoamperometryen
dc.titleNucleation and early stages of growth of lead onto copper electrodes from dilute electrolytesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСтевановић, Сања; Николић, Небојша; Бранковиц, Горан;
dc.citation.volume26
dc.citation.issue12
dc.citation.spage3274
dc.citation.epage3282
dc.citation.other26(12): 3274-3282
dc.citation.rankM22
dc.identifier.doi10.1016/S1003-6326(16)64461-8
dc.identifier.rcubConv_3674
dc.identifier.scopus2-s2.0-85009074673
dc.identifier.wos000393305900024
dc.type.versionpublishedVersion


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