Show simple item record

dc.creatorKaluđerović, Goran N.
dc.creatorHernandez-Corroto, Esther
dc.creatorBrandt, Wolfgang
dc.creatorZmejkovski, Bojana
dc.creatorGomez-Ruizb, Santiago
dc.date.accessioned2019-01-30T17:51:40Z
dc.date.available2019-01-30T17:51:40Z
dc.date.issued2016
dc.identifier.issn0095-8972
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2014
dc.description.abstractFour palladium(II) complexes with R-2 edda ligands, dichlorido(O,O-dialkylethylenediamine-N,N'-diacetate)palladium(II) monohydrates, [PdCl2(R(2)edda)].H2O, R=Me, Et, n-Pr, i-Bu, and the new ligand precursor i-Bu(2)edda.2HCl.H2O, O,O-diisobutylethylenediamine-N,N'-diacetate dihydrochloride monohydrate, were synthesized and characterized by IR, H-1 and C-13 NMR spectroscopy, and elemental analysis. DFT calculations were performed for the palladium(II) complexes and a high possibility for isomer formation due to stereogenic N ligand atoms was confirmed. Moreover, DFT simulations revealed energetic profile of isomer formation. Computational outcomes are in agreement with spectroscopic instrumental findings, both strongly indicating a non-stereoselective reaction between selected esters and K-2[PdCl4], forming isomers. [GRAPHICS]en
dc.publisherTaylor & Francis Ltd, Abingdon
dc.relationMinisterio de Economia y Competitividad, Spain - CTQ2012-30762
dc.relationUniversidad Rey Juan Carlos-Banco de Santander - Excellence Group QUINANOAP
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Coordination Chemistry
dc.subjectPalladium(II) complexesen
dc.subjectR-2 edda ligandsen
dc.subjectdiastereoisomersen
dc.subjectDFTen
dc.titlePalladium(II) complexes with R-2 edda-derived ligandsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractХернандез-Цоррото, Естхер; Калудеровиц, Горан Н; Змејковски, Бојана; Брандт, Wолфганг; Гомез-Руизб, Сантиаго;
dc.citation.volume69
dc.citation.issue8
dc.citation.spage1337
dc.citation.epage1345
dc.citation.other69(8): 1337-1345
dc.citation.rankM22
dc.identifier.doi10.1080/00958972.2016.1168519
dc.identifier.rcubConv_3531
dc.identifier.scopus2-s2.0-84964034012
dc.identifier.wos000375481700004
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record