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Remote functionalisation by ferrous ion-cupric ion induced decomposition of alkyl hydroperoxides
(Pergamon Press, 1979)
By decomposition of alkyl hydroperoxides 1-8 with ferrous sulfate-cupric acetate reagent, intramolecular functionalisation of remote non-activated C atom takes place and unsaturated alcohols with double bond mainly at ...
Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms
(Pergamon Press, 1979)
Hydrogen evolution on rotating platinum electrode has been measured in the presence of Pb, Tl and Cd adatoms. At low coverages of these adatoms (θM < 0.5) the mechanism of H2 evolution is the same as that for Pt, giving ...
Effect of codeposition of polymer on the morphology of electrodeposited copper
(Kluwer Academic Publishers, 1979)
Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep ...
Electrocatalysis on Surfaces Modified by Foreign Metal Adatoms
(WILEY‐VCH, 1979)
An approach to the problem of electrocatalysis, which consists of modification of electrode surfaces by foreign metal adatoms, is presented. The paper reviews the work done in the author's lab on the effects of foreign ...
Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 5-p-nitrobenzoates
(Pergamon Press, 1979)
The solvolysis of (Z)- and (E)-3β-acyloxy-5,10-seco-1(10)-cholesten-5β-ol p-nitrobenzoates 4 and 5 has been investigated and compared with the solvolytic reactivity of the epimeric (Z)- and (E)-5α-p-nitrobenzoates 1 and ...
Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
X-ray and carbon-13 nuclear magnetic resonance characterization of cyclopropane derivatives obtained by solvolysis of (E)-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates
(Pergamon Press, 1979)
The stereochemistries and conformations of the cyclopropane ring containing compounds derived from (E-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates have been determined by X-ray methods and the results ...
The critical overpotential for zinc dendrite formation
(Kluwer Academic Publishers, 1979)
The critical overpotential for zinc dendrite growth is determined as 173 mV by the method described by Popov et al. [1]. It was shown that this procedure can be applied successfully to metal deposition processes when there ...
Optical and electrochemical study of electrocatalysis by foreign metal adatoms. Oxidation of formic acid on rhodium
(Elsevier Sequoia S.A., 1979)
Specular reflectance spectroscopy, in conjunction with linear potential sweep voltammetry, has been used in studying catalytic effects of Pb and Cd adatoms on the oxidation of HCOOH on Rh. The intermediates formed in that ...
The dissolution of iron under cathodic polarization
(Pergamon Press, 1979)
It has been shown that the dissolution rate for iron at cathodic potential is higher than expected on the grounds of the Wagner-Traud mixed potential theory. This observation cannot be explained by a parallel chemical ...