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Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
X-ray and carbon-13 nuclear magnetic resonance characterization of cyclopropane derivatives obtained by solvolysis of (E)-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates
(Pergamon Press, 1979)
The stereochemistries and conformations of the cyclopropane ring containing compounds derived from (E-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates have been determined by X-ray methods and the results ...
Mass spectrometric analysis of plasma composition of a D. C. arc burning in an air atmosphere / Massenspektrometrische Analyse der Plasmazusammensetzung eines Gleichstrombogens in Luft
(Springer-Verlag, 1979)
The plasma composition of a d. c. arc burning in air was investigated by mass spectrometry. It has been found that the CO and CO2 contents result from homogenous chemical reactions and that the content of carbon is about ...
Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 5-p-nitrobenzoates
(Pergamon Press, 1979)
The solvolysis of (Z)- and (E)-3β-acyloxy-5,10-seco-1(10)-cholesten-5β-ol p-nitrobenzoates 4 and 5 has been investigated and compared with the solvolytic reactivity of the epimeric (Z)- and (E)-5α-p-nitrobenzoates 1 and ...