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An analysis of elementary processes of water desorption from zeolites of type a Part II. Zeolites with bivalent counterions
(Elsevier, 1976)
DSC and EGA were used to follow the process of water desorption from synthetic MgA, ZnA and CdA zeolites. Applying a semi-empirical algorithm the complex experimental curves were resolved into elementary ones. It turned ...
Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
(Royal Society of Chemistry, 1979)
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
Individual ionic activities and mass transfer in anodic chlorate formation
(Switzerland : Springer Nature, 1973)
The individual activity of hypochlorite ion in concentrated neutral salt (NaCl-NaClO3) solutions has been estimated kinetically by measurement of the Faradaic efficiency in a chlorate producing system comprised of a cell ...
Multiphoton resonance absorption characteristics
(IOP Publishing, 1977)
It is shown that the Dyson equation gives finite values for multiphoton resonance absorption rates when an appropriate diagram summation technique is applied. A simple recurrence formula connects the n-photon absorption ...
Direct solution analysis using an arc source incorporating two plasmas rotating in a graphite tube
(Elsevier, 1977)
As a continuation of earlier work on arc sources for the spectrochemical analysis of powdered samples, a source appropriate for multi-element analysis of trace elements in solution has been developed. The nebulized solution ...
Acetoxylation of steroidal lactones by means of lead tetraacetate
(Elsevier, 1970)
One of the structural features of many bitter principles ls the presence of a &-lactone ring. Some of these compounds differ from one another by the state of oxidation of the molecule as a whole and also by the state of ...
Effect of codeposition of polymer on the morphology of electrodeposited copper
(Kluwer Academic Publishers, 1979)
Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep ...
Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms
(Pergamon Press, 1979)
Hydrogen evolution on rotating platinum electrode has been measured in the presence of Pb, Tl and Cd adatoms. At low coverages of these adatoms (θM < 0.5) the mechanism of H2 evolution is the same as that for Pt, giving ...
Optical and electrochemical study of electrocatalysis by foreign metal adatoms. Oxidation of formic acid on rhodium
(Elsevier Sequoia S.A., 1979)
Specular reflectance spectroscopy, in conjunction with linear potential sweep voltammetry, has been used in studying catalytic effects of Pb and Cd adatoms on the oxidation of HCOOH on Rh. The intermediates formed in that ...
Remote functionalisation by ferrous ion-cupric ion induced decomposition of alkyl hydroperoxides
(Pergamon Press, 1979)
By decomposition of alkyl hydroperoxides 1-8 with ferrous sulfate-cupric acetate reagent, intramolecular functionalisation of remote non-activated C atom takes place and unsaturated alcohols with double bond mainly at ...