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Rotating two-ring electrodes as a tool for electrochemical investigations of gas-evolving reactions
(Elsevier, 1972)
It is shown that two concentric ring electrodes located on a rotating disc surface can be used as an instrument for chemical and electrochemical analysis of gas-evolving reactions up to rates of gas evolution from the inner ...
The polarographic behavior of metal ions in molten LiNO3-KNO3 eutectic in presence of complexon III
(Elsevier, 1973)
The possibility of using complexon III as a complexing substance in the polarography of salt metls (LiNO3-KNO3 eutectic) has been investigated. Complexon III was found to form complexes with Cd, Pb, Ni and Zn ions in the ...
Pulsating potential electrolysis in the deposition of copper
(Elsevier, 1973)
A very low impedance circuit was constructed in order to provide a pulsating cathodic potential for a copper electrode immersed in a copper sulphate solution of the type used in copper refining. The increase in surface ...
Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...
On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media
(Elsevier, 1977)
The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange ...
Studies of the deposition of cadmium on foreign substrates
(Elsevier, 1977)
Cadmium deposition on nickel, lead, silver, gold and copper has been studied by the potential sweep and potentiostatic method with a simultaneous observation of the surface by optical microscopy. It was found that the ...
A Conductometric Study of the Bi-HgI2 System
(De Gruyter, 1976)
The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms ...
Kinetics and mechanism of deposition of zinc from zincate in concentrated alkali hydroxide solutions
(Elsevier, 1976)
Galvanostatic investigation has been carried out of the kinetics of the reaction on zinc amalgam hanging mercury drop immersed in alkaline zincate solutions at KOH concentrations ranging from 1 to 14 normal. Three kinds ...
Criteria for the determination of the stereochemistry of steroidal indolizidines
(Elsevier, 1974)
E/F-Indolizidine steroids, which represent a structural unit of Solanum alkaloids, have been synthesized and used to evaluate criteria (IR—Bohlmann bands,1a-c —hydrogenbond,2a-e NMR,3a-c mass spectra,4 kinetic studies of ...
Electric conductivity and viscosity of 1,4-benzenediol and hydroxybenzene solutions in concentrated sulphuric acid
(Elsevier, 1974)
Many authors have dealt with the formation of the complexes of 1,4-benzenediol and some metals in concentrated sulphuric acid. However, no data can be found in the literature either on the reaction of 1,4-benzenediol with ...