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dc.creatorPantelic, Nebojsa
dc.creatorStanković, Dalibor
dc.creatorZmejkovski, Bojana
dc.creatorKaluđerović, Goran N.
dc.creatorSabo, Tibor
dc.date.accessioned2019-01-30T17:50:38Z
dc.date.available2019-01-30T17:50:38Z
dc.date.issued2016
dc.identifier.issn1452-3981
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1963
dc.description.abstractOxidation-reduction properties of eleven gold(III) complexes with (S,S)-R(2)edda-type ligands was studied by cyclic and differential pulse voltammetry in DMSO. Series I: [AuCl2{(S,S)-R(2)eddip}]PF6, (S,S)-eddip = (S,S)-ethylenediamine-N,N'-di-2-propanoate, R = n-butyl, n-pentyl, isobutyl, isoamyl, cyclopentyl, 1-5; II: [AuCl2{(S,S)-R(2)eddch}]PF6, (S,S)-eddch = (S,S)-ethylenediamine-N,N'-di-2-(3-cyclohexyl)propanoate, R = methyl, ethyl, n-propyl, n-butyl, isobutyl, isoamyl, 6-11. Voltammograms in DMSO showed two successive irreversible reduction steps, where Au-I species were the final reduction product. Reduction potential values are in range from 116 to 156 mV (Ep(1)) and -520 to -572 mV (Ep(2)) for Series I and from 148 to 228 mV (Ep(1)) and -569 to -638 mV (Ep(2)) for Series II. In general, slightly easier reduction of complexes belonging to Series I (higher cytotoxicity) could be due to less steric hindrance around the gold center. Reduction potentials and anticancer activity are not in correlation.en
dc.publisherEsg, Belgrade
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172030/RS//
dc.rightsopenAccess
dc.sourceInternational Journal of Electrochemical Science
dc.subjectgold(III) complexesen
dc.subjectR(2)edda-type ligandsen
dc.subjectanticancer activityen
dc.subjectreduction potentialen
dc.subjectvoltammetryen
dc.titleElectrochemical properties of some gold(III) complexes with (S,S)-R(2)edda-type ligandsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСабо, Тибор Ј; Станковиц, Далибор М; Змејковски, Бојана; Калудеровиц, Горан Н; Пантелиц, Небојса;
dc.citation.volume11
dc.citation.issue2
dc.citation.spage1162
dc.citation.epage1171
dc.citation.other11(2): 1162-1171
dc.citation.rankM23
dc.identifier.rcubConv_3498
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/14694/110201162.pdf
dc.identifier.wos000371091400025
dc.type.versionpublishedVersion


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