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Decarbonylative Dibromination of 5-Phenylthiophene-2-carbaldehyde with Bromine
dc.creator | Ajdačić, Vladimir | |
dc.creator | Stepanović, Stepan | |
dc.creator | Zlatović, Mario | |
dc.creator | Gruden, Maja | |
dc.creator | Opsenica, Igor | |
dc.date.accessioned | 2019-01-30T17:50:20Z | |
dc.date.available | 2019-01-30T17:50:20Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 0039-7881 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/1951 | |
dc.description.abstract | The decarbonylative dibromination of 2-thiophenecarboxaldehyde derivatives with bromine under mild conditions is developed. The mechanism for the decarbonylation is investigated by experimental and instrumental techniques and is extended by a computational study. Alongside removal of the formyl group, this method enables functionalization of the starting compounds in a single reaction step, which can be further exploited for the synthesis of 2,5-diaryl-3-bromothiophenes and 2,3,5-triarylthiophenes. | en |
dc.publisher | Georg Thieme Verlag Kg, Stuttgart | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172008/RS// | |
dc.relation | Serbian Academy of Sciences and Arts | |
dc.rights | restrictedAccess | |
dc.source | Synthesis | |
dc.subject | deformylation | en |
dc.subject | thiophene | en |
dc.subject | reaction mechanism | en |
dc.subject | Wheland intermediate | en |
dc.subject | Suzuki-Miyaura reaction | en |
dc.title | Decarbonylative Dibromination of 5-Phenylthiophene-2-carbaldehyde with Bromine | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Груден, Маја; Опсениц, Игор М.; Aјдачић, Владимир; Златовиц, Марио; Степановић, Степан; | |
dc.citation.volume | 48 | |
dc.citation.issue | 24 | |
dc.citation.spage | 4423 | |
dc.citation.epage | 4430 | |
dc.citation.other | 48(24): 4423-4430 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1055/s-0035-1562615 | |
dc.identifier.scopus | 2-s2.0-84983785815 | |
dc.identifier.wos | 000389330400005 | |
dc.type.version | publishedVersion |