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Decarbonylative Dibromination of 5-Phenylthiophene-2-carbaldehyde with Bromine

dc.creatorAjdačić, Vladimir
dc.creatorStepanović, Stepan
dc.creatorZlatović, Mario
dc.creatorGruden, Maja
dc.creatorOpsenica, Igor
dc.date.accessioned2019-01-30T17:50:20Z
dc.date.available2019-01-30T17:50:20Z
dc.date.issued2016
dc.identifier.issn0039-7881
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/1951
dc.description.abstractThe decarbonylative dibromination of 2-thiophenecarboxaldehyde derivatives with bromine under mild conditions is developed. The mechanism for the decarbonylation is investigated by experimental and instrumental techniques and is extended by a computational study. Alongside removal of the formyl group, this method enables functionalization of the starting compounds in a single reaction step, which can be further exploited for the synthesis of 2,5-diaryl-3-bromothiophenes and 2,3,5-triarylthiophenes.en
dc.publisherGeorg Thieme Verlag Kg, Stuttgart
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172008/RS//
dc.relationSerbian Academy of Sciences and Arts
dc.rightsrestrictedAccess
dc.sourceSynthesis
dc.subjectdeformylationen
dc.subjectthiopheneen
dc.subjectreaction mechanismen
dc.subjectWheland intermediateen
dc.subjectSuzuki-Miyaura reactionen
dc.titleDecarbonylative Dibromination of 5-Phenylthiophene-2-carbaldehyde with Bromineen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractГруден, Маја; Опсениц, Игор М.; Aјдачић, Владимир; Златовиц, Марио; Степановић, Степан;
dc.citation.volume48
dc.citation.issue24
dc.citation.spage4423
dc.citation.epage4430
dc.citation.other48(24): 4423-4430
dc.citation.rankM22
dc.identifier.doi10.1055/s-0035-1562615
dc.identifier.scopus2-s2.0-84983785815
dc.identifier.wos000389330400005
dc.type.versionpublishedVersion


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