Spontaneously Deposited Rh on Au(111) Observed by AFM and XPS: Electrocatalysis of Hydrogen Evolution
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2016
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Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Rhodium nanoislands were spontaneously deposited on Au(111) up to a full coverage. Obtained Rh/Au(111) bimetallic surface was characterized ex situ by Atomic Force Microscopy imaging and by X-Ray Photoelectron Microscopy, while in situ characterization was performed by Cyclic Voltammetry in 0.1 M NaOH solution. Pronounced catalysis of hydrogen evolution reaction has been observed on Rh modified Au(111) surface compared to bare Au(111). This is ascribed to the suitable geometry of obtained Rh/Au(111) nanostructured electrode surface providing large number of active sites and to the electronic interaction between Au(111) substrate and Rh deposit.
Izvor:
Journal of the Electrochemical Society, 2016, 163, 12Izdavač:
- Electrochemical Soc Inc, Pennington
Finansiranje / projekti:
- Funkcionalni, funkcionalizovani i usavršeni nano materijali (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
DOI: 10.1149/2.0041612jes
ISSN: 0013-4651
WoS: 000389151300006
Scopus: 2-s2.0-84994572073
Institucija/grupa
IHTMTY - JOUR AU - Štrbac, Svetlana AU - Smiljanić, Milutin AU - Rakočević, Zlatko Lj. PY - 2016 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1950 AB - Rhodium nanoislands were spontaneously deposited on Au(111) up to a full coverage. Obtained Rh/Au(111) bimetallic surface was characterized ex situ by Atomic Force Microscopy imaging and by X-Ray Photoelectron Microscopy, while in situ characterization was performed by Cyclic Voltammetry in 0.1 M NaOH solution. Pronounced catalysis of hydrogen evolution reaction has been observed on Rh modified Au(111) surface compared to bare Au(111). This is ascribed to the suitable geometry of obtained Rh/Au(111) nanostructured electrode surface providing large number of active sites and to the electronic interaction between Au(111) substrate and Rh deposit. PB - Electrochemical Soc Inc, Pennington T2 - Journal of the Electrochemical Society T1 - Spontaneously Deposited Rh on Au(111) Observed by AFM and XPS: Electrocatalysis of Hydrogen Evolution VL - 163 IS - 12 DO - 10.1149/2.0041612jes ER -
@article{ author = "Štrbac, Svetlana and Smiljanić, Milutin and Rakočević, Zlatko Lj.", year = "2016", abstract = "Rhodium nanoislands were spontaneously deposited on Au(111) up to a full coverage. Obtained Rh/Au(111) bimetallic surface was characterized ex situ by Atomic Force Microscopy imaging and by X-Ray Photoelectron Microscopy, while in situ characterization was performed by Cyclic Voltammetry in 0.1 M NaOH solution. Pronounced catalysis of hydrogen evolution reaction has been observed on Rh modified Au(111) surface compared to bare Au(111). This is ascribed to the suitable geometry of obtained Rh/Au(111) nanostructured electrode surface providing large number of active sites and to the electronic interaction between Au(111) substrate and Rh deposit.", publisher = "Electrochemical Soc Inc, Pennington", journal = "Journal of the Electrochemical Society", title = "Spontaneously Deposited Rh on Au(111) Observed by AFM and XPS: Electrocatalysis of Hydrogen Evolution", volume = "163", number = "12", doi = "10.1149/2.0041612jes" }
Štrbac, S., Smiljanić, M.,& Rakočević, Z. Lj.. (2016). Spontaneously Deposited Rh on Au(111) Observed by AFM and XPS: Electrocatalysis of Hydrogen Evolution. in Journal of the Electrochemical Society Electrochemical Soc Inc, Pennington., 163(12). https://doi.org/10.1149/2.0041612jes
Štrbac S, Smiljanić M, Rakočević ZL. Spontaneously Deposited Rh on Au(111) Observed by AFM and XPS: Electrocatalysis of Hydrogen Evolution. in Journal of the Electrochemical Society. 2016;163(12). doi:10.1149/2.0041612jes .
Štrbac, Svetlana, Smiljanić, Milutin, Rakočević, Zlatko Lj., "Spontaneously Deposited Rh on Au(111) Observed by AFM and XPS: Electrocatalysis of Hydrogen Evolution" in Journal of the Electrochemical Society, 163, no. 12 (2016), https://doi.org/10.1149/2.0041612jes . .