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dc.creatorNastasović, Aleksandra
dc.creatorEkmeščić, Bojana
dc.creatorSandić, Zvjezdana P.
dc.creatorRandjelović, Danijela
dc.creatorMozetic, Miran
dc.creatorVesel, Alenka
dc.creatorOnjia, Antonije E.
dc.date.accessioned2019-01-30T17:48:52Z
dc.date.available2019-01-30T17:48:52Z
dc.date.issued2016
dc.identifier.issn0169-4332
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/1881
dc.description.abstractThe mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) functionalized by reaction of the pendant epoxy groups with diethylene triamine (PGME-deta) was studied using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analysis. Atomic force microscopy (AFM) and scanning energy-dispersive X-ray spectroscopy (SEM-EDX) were used for the determination of surface morphology of the copolymer particles. The sorption behavior of heavy metals Cu(II), Cd(II) and Pb(II) ions sorption was investigated in batch static experiments under non-competitive conditions at room temperature (298 K). The obtained results were fitted to pseudo-first order, pseudo-second order and intraparticle diffusion kinetic model. The kinetics studies showed that Cu(II), Cd(II) and Pb(II) sorption obeys the pseudo-second-order model under all investigated operating conditions with evident influence of pore diffusion.en
dc.publisherElsevier
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/32008/RS//
dc.relationMinistry of Education, Science and Technological Development of the Republic of Serbia - 37201
dc.relationSlovenian Research Agency - P2-0082
dc.rightsrestrictedAccess
dc.sourceApplied Surface Science
dc.subjectDiethylene triamineen
dc.subjectGlycidyl methacrylate copolymeren
dc.subjectHeavy metalsen
dc.subjectXPSen
dc.subjectAFMen
dc.subjectKinetics modelsen
dc.titleMechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)en
dc.typearticle
dc.rights.licenseARR
dcterms.abstractОњиа, Aнтоније Е; Екмешчић, Бојана; Настасовић, Aлександра; Ранђеловић, Данијела; Сандиц, Звјездана П; Весел, Aленка; Мозетиц, Миран;
dc.citation.volume385
dc.citation.spage605
dc.citation.epage615
dc.citation.other385: 605-615
dc.citation.rankaM21
dc.identifier.doi10.1016/j.apsusc.2016.05.165
dc.identifier.scopus2-s2.0-85009213495
dc.identifier.wos000380825900071
dc.type.versionpublishedVersion


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