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dc.creatorMaksic, A
dc.creatorSmiljanić, Milutin
dc.creatorMiljanic, S
dc.creatorRakočević, Zlatko Lj.
dc.creatorŠtrbac, Svetlana
dc.date.accessioned2019-01-30T17:48:19Z
dc.date.available2019-01-30T17:48:19Z
dc.date.issued2016
dc.identifier.issn0013-4686
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/1852
dc.description.abstractBimetallic electrodes prepared by Rh nanoislands spontaneously deposited on polycrystalline palladium, Pd(poly), at submonolayer coverage were explored for ethanol oxidation in alkaline media. Characterization of obtained Rh/Pd(poly) nanostructures was performed ex situ by AFM imaging and by X-ray photoelectron spectroscopy. In situ characterization of the obtained electrodes and subsequent ethanol oxidation measurements were performed by cyclic voltammetry in 0.1 M KOH. Palladium surface with 50% Rh coverage exhibited the highest catalytic activity for ethanol oxidation in alkaline media. The origin of the enhanced catalysis of Rh/Pd(poly) surfaces with respect to bare Pd was explained by the electronic effect. Possible reaction pathways for ethanol oxidation were discussed taking into account the activity of obtained bimetallic electrodes for the oxidation of CO and acetaldehyde, as the most probable reaction intermediates.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45005/RS//
dc.rightsrestrictedAccess
dc.sourceElectrochimica Acta
dc.subjectpalladiumen
dc.subjectrhodiumen
dc.subjectAFMen
dc.subjectXPSen
dc.subjectethanol oxidationen
dc.titleEthanol Oxidation on Rh/Pd(poly) in Alkaline Solutionen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractРакочевић, Златко Љ.; Максиц, A; Штрбац, Светлана; Смиљанић, Милутин; Миљаниц, С;
dc.citation.volume209
dc.citation.spage323
dc.citation.epage331
dc.citation.other209: 323-331
dc.citation.rankM21
dc.identifier.doi10.1016/j.electacta.2016.05.096
dc.identifier.rcubConv_3563
dc.identifier.scopus2-s2.0-84991518521
dc.identifier.wos000379504600037
dc.type.versionpublishedVersion


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