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Study of the intramolecular Heck reaction: synthesis of the bicyclic core of corialstonidine
dc.creator | Tasic, Gordana | |
dc.creator | Maslak, Veselin | |
dc.creator | Husinec, Suren | |
dc.creator | Todorović, Nina | |
dc.creator | Savić, Vladimir | |
dc.date.accessioned | 2019-01-30T17:46:00Z | |
dc.date.available | 2019-01-30T17:46:00Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0040-4039 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/1740 | |
dc.description.abstract | The intramolecular Heck reaction has been examined for the preparation of the core bicyclic structure of corialstonidine. Initial attempts to cyclise a vinyl iodide moiety onto a cyclic allyl alcohol were complicated by various side reactions. However, the corresponding process performed under reductive conditions on a conjugated ketone, obtained from the cyclic allyl alcohol, afforded the desired bicyclo[3.2.1] derivative. This compound possesses the skeletal features of the carbocyclic fragment of corialstonidine and is suitable for further transformations aimed towards the synthesis of the natural product or its derivatives. | en |
dc.publisher | Oxford : Pergamon-Elsevier Science Ltd | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172009/RS// | |
dc.rights | restrictedAccess | |
dc.source | Tetrahedron Letters | |
dc.subject | Heck reaction | en |
dc.subject | Corialstonidine | en |
dc.subject | Bicyclic ketone | en |
dc.title | Study of the intramolecular Heck reaction: synthesis of the bicyclic core of corialstonidine | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Маслак, Веселин; Тасиц, Гордана; Хусинец, Сурен; Тодоровић, Нина; Савиц, Владимир; | |
dc.citation.volume | 56 | |
dc.citation.issue | 19 | |
dc.citation.spage | 2529 | |
dc.citation.epage | 2532 | |
dc.citation.other | 56(19): 2529-2532 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1016/j.tetlet.2015.03.129 | |
dc.identifier.scopus | 2-s2.0-84937762963 | |
dc.identifier.wos | 000353751000035 | |
dc.type.version | publishedVersion |