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dc.creatorRašović, Aleksandar
dc.creatorKoch, Andreas
dc.creatorKleinpeter, Erich
dc.creatorMarković, Rade
dc.date.accessioned2019-01-30T17:35:12Z
dc.date.available2019-01-30T17:35:12Z
dc.date.issued2013
dc.identifier.issn0040-4020
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/1227
dc.description.abstractTrithiaazapentalene derivatives were prepared by the reaction of 2-alkylidene-4-oxothiazolidines with Lawesson's reagent. They are classified as two structurally different trithiaazapentalene compounds that have different contributions of monocyclic 1,2-dithiole and 1,2,4-dithiazole structures and degrees of aromaticity of the bicyclic trithiaazapentalene system. The electron-donating ability of substituents at the C(5) position of the trithiaazapentalene system is recognized as the main cause for changes in pi-Celectron distribution. This is the first complete study of substituent effects on the structure of trithiapentalenes.en
dc.publisherOxford : Pergamon-Elsevier Science Ltd
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS//
dc.relationDeutscher Akademischer Austauschdienst (DAAD)-project - 504 252 70
dc.rightsrestrictedAccess
dc.sourceTetrahedron
dc.subjectTrithiapentaleneen
dc.subject1,2-Dithioleen
dc.subject1,2,4-Dithiazoleen
dc.subject4-Oxothiazolidineen
dc.subjectRearrangement to trithiaazapentaleneen
dc.subjectPush-pull characteren
dc.titleStudies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivativesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractКоцх, Aндреас; Клеинпетер, Ерицх; Марковиц, Раде; Рашовић, Aлександар;
dc.citation.volume69
dc.citation.issue51
dc.citation.spage10849
dc.citation.epage10857
dc.citation.other69(51): 10849-10857
dc.citation.rankM21
dc.identifier.doi10.1016/j.tet.2013.10.088
dc.identifier.scopus2-s2.0-84888646581
dc.identifier.wos000328808300009
dc.type.versionpublishedVersion


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