Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate
Samo za registrovane korisnike
2012
Autori
Čobeljić, BožidarWarzajtis, Beata
Rychlewska, Urszula
Radanović, Dušanka
Spasojević, Vojislav
Sladić, Dušan
Eshkourfu, Rabia
Anđelković, Katarina
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A new malonic dihydrazide-based ligand, N',N'(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K.
Ključne reči:
Ni(II) complexes / X-ray structure / Intramolecular interactionsIzvor:
Journal of Coordination Chemistry, 2012, 65, 4, 655-667Izdavač:
- Taylor & Francis Ltd, Abingdon
Finansiranje / projekti:
- Interakcije prirodnih proizvoda, njihovih derivata i kompleksnih jedinjenja sa proteinima i nukleinskim kiselinama (RS-MESTD-Basic Research (BR or ON)-172055)
DOI: 10.1080/00958972.2012.658778
ISSN: 0095-8972
WoS: 000302036000008
Scopus: 2-s2.0-84861554734
Institucija/grupa
IHTMTY - JOUR AU - Čobeljić, Božidar AU - Warzajtis, Beata AU - Rychlewska, Urszula AU - Radanović, Dušanka AU - Spasojević, Vojislav AU - Sladić, Dušan AU - Eshkourfu, Rabia AU - Anđelković, Katarina PY - 2012 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1041 AB - A new malonic dihydrazide-based ligand, N',N'(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate VL - 65 IS - 4 SP - 655 EP - 667 DO - 10.1080/00958972.2012.658778 ER -
@article{ author = "Čobeljić, Božidar and Warzajtis, Beata and Rychlewska, Urszula and Radanović, Dušanka and Spasojević, Vojislav and Sladić, Dušan and Eshkourfu, Rabia and Anđelković, Katarina", year = "2012", abstract = "A new malonic dihydrazide-based ligand, N',N'(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate", volume = "65", number = "4", pages = "655-667", doi = "10.1080/00958972.2012.658778" }
Čobeljić, B., Warzajtis, B., Rychlewska, U., Radanović, D., Spasojević, V., Sladić, D., Eshkourfu, R.,& Anđelković, K.. (2012). Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 65(4), 655-667. https://doi.org/10.1080/00958972.2012.658778
Čobeljić B, Warzajtis B, Rychlewska U, Radanović D, Spasojević V, Sladić D, Eshkourfu R, Anđelković K. Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate. in Journal of Coordination Chemistry. 2012;65(4):655-667. doi:10.1080/00958972.2012.658778 .
Čobeljić, Božidar, Warzajtis, Beata, Rychlewska, Urszula, Radanović, Dušanka, Spasojević, Vojislav, Sladić, Dušan, Eshkourfu, Rabia, Anđelković, Katarina, "Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate" in Journal of Coordination Chemistry, 65, no. 4 (2012):655-667, https://doi.org/10.1080/00958972.2012.658778 . .