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Oxygen reduction on iron-IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions
(Elsevier, 1991)
The kinetics of hydrogen peroxide reduction were studied on iron in borate buffered and unbuffered solutions of pH ranging from 8.6 to 13.8, with and without the presence of chloride ions. A rotating disk electrode was ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Depolarization end point can glassy carbon electrodes: Microscale coulometry of thioglycollic acid
(Wiley, 1991)
An externally unpolarized twin couple of glassy carbon electrodes, undergoing different pretreatments, and connected to nothing but a recorder, was engaged for simple and fast end‐point detection of electrometric titrations ...
Electrodeposition of silver powder by pulsating and reversing currents
(Springer Nature Switzerland AG 2020, 1991)
The effect of the shape of the current wave and frequency in silver deposition by pulsating and reversing currents on the morphology of powder particles were investigated. The possibility of obtaining particles with different ...
Electrosorption of hydrogen and sulfuric acid anions on single crystal platinum stepped surfaces. Part II. The [110] zone
(Elsevier, 1991)
Hydrogen and bisulphate adsorption at platinum single crystal surfaces from the [ITO] zone is
strongly dependent on the crystallographic orientation of the electrode surface, which is similar to that
found earlier for ...
Oxidative hydrolysis and acid-catalyzed rearrangement of steroidal isoxazolidines
(Elsevier, 1991)
Treatment of steroidal isoxazolidines 3a, 3b and 5b with N-methylhydroxylamine hydrochloride in boiling ethanol-pyridine (1:1) solution results in elimination of the CH3NH2fragment, affording products of oxidative hydrolysis ...
The electro-oxidation of glycerol on the gold(100)-oriented single-crystal surface and poly crystalline surface in 0.1 M NaOH
(Elsevier, 1991)
Studies of chemical and electrochemical reactions at well-defined surfaces provide additional data on surface reactivity and guidelines for the understanding and design of catalytic materials. In this work, the oxidation ...
Formation of allenes by reaction of 1,4-dibromobut-2-ene with dialkyl ketones and base
(Royal Society of Chemistry, 1991)
By reaction of 1,4-dibromo-(E)-but-2-ene with dialkyl ketones and sodium hydride the allenic ketones 3 were obtained as the main products, in addition to the symmetrical unsaturated 1,8-diketones 4.
Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides
(Springer, 1991)
Carbon monoxide oxidation activity and aging of Cu1-xCrxCo2O4 (0<x<1) spinels in the presence of sulfur oxides have been studied. The results obtained indicate that the sulfur tolerance is related to the presence of ...
Non-sensitized photooxygenation of some steroidal isoxazolidines
(Pergamon press, 1991)
UV irradiation of the steroidal isoxazolidines 2a, 2b, and 2c in various solvents in the presence of molecular oxygen, results in oxidative cleavage of the epoxyimino bridge to give several products; the N-unsubstituted ...