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Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction
(Elsevier, 1987)
Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the ...
Transition metal catalysts for porous carbon air-electrodes in neutral chloride electrolytes
(Springer Nature, 1983)
Porous carbon air-electrodes activated by CoPC, FePHP, PdPC, PtPC and metal-free PC were studied in 2 mol dm-3 NaCl electrolyte. The activity of heat-treated carbon activated by CoPC was compared to carbon activated by in ...
Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives
(Elsevier, 1985)
Thermal decomposition of steroidal 5α,8α-peroxides (such as 1) resulted in bisfragmentation of the C(5)-C(10) and C(8)-C(9) bonds, and elimination of acetic acid, to produce a new type of bicyclic compounds, namely ...
The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics
(Switzerland : Springer Nature, 1984)
It is shown that good quality deposits of cobalt-molybdenum alloys may be produced using pulse plating and it is demonstrated that such coatings on titanium have a low overpotential for hydrogen evolution under typical ...
Correlative geochemical study of crude oils from southeastern and southern parts of the Pannonian Basin
(Organic Geochemistry, 1988)
Several crude oils from the southeastern Yugoslav part of the Pannonian Basin are correlated for the first time on the basis of many bulk and specific parameters. The investigations involved 15 oils from oil-gas fields A ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode. Part I. Theory
(Elsevier, 1987)
A general scheme of oxygen reduction is given and analysis of the disk-ring measurements is performed. Expressions for the diagnostic criteria for such a scheme have been derived and their implications are discussed. The ...
Free-radical oxidative transformations of androst-4-ene-3β,9α,17β-triol 3,17-diacetate
(Tetrahedron, 1988)
The oxidation of androst-4-ene-3β,9α,17β-triol 3,17-diacetate (2) with lead tetraacetate resulted mainly In β-fragmentation of the C(9)-C(10) bond to give a mixture of 10α- and 10β-acetoxy-Δ4-unsaturated 9,10-seco-steroidal ...
Synthesis, structure, and reactions of secosteroids containing a medium-sized ring. Part 17. Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 3-tosylates
(Royal Society of Chemistry, 1980)
Kinetic measurements of the solvolysis of (Z)-3α- and (Z)-3β-, and (E)-3α- and (E)-3β-tosyloxy-5,10-secocholest-1(10)-en-5-ones in buffered aqueous acetone (90 : 10 v/v) reveal that the (Z)-3α-, (E)-3α-, and (E)-3β-tosylates ...
Circular dichroism of some cyclopropane ring containing 1,3-cyclo-5,10-seco-steroidal ketones
(Elsevier, 1982)
Circular dichroism of the rearranged keto steroids 3 and 4, containing a condensed three and nine-membered ring system, shows that the conformation of the nine-membered ring is the same in solution as in the crystal; ...